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Libby and James Arnold proceeded to test the radiocarbon dating theory by analyzing samples with known ages.
For example, two samples taken from the tombs of two Egyptian kings, Zoser and Sneferu, independently dated to 2625 BC plus or minus 75 years, were dated by radiocarbon measurement to an average of 2800 BC plus or minus 250 years. Carbon dioxide produced in this way diffuses in the atmosphere, is dissolved in the ocean, and is taken up by plants via photosynthesis.
Other corrections must be made to account for the proportion of throughout the biosphere (reservoir effects).
They synthesized Libby and several collaborators proceeded to experiment with methane collected from sewage works in Baltimore, and after isotopically enriching their samples they were able to demonstrate that they contained radioactive .
For consistency with these early papers, and to avoid the risk of a double correction for the incorrect half-life, radiocarbon ages are still calculated using the incorrect half-life value.
A correction for the half-life is incorporated into calibration curves, so even though radiocarbon ages are calculated using a half-life value that is known to be incorrect, the final reported calibrated date, in calendar years, is accurate.
the average or expected time a given atom will survive before undergoing radioactive decay. The calculations involve several steps and include an intermediate value called the "radiocarbon age", which is the age in "radiocarbon years" of the sample: an age quoted in radiocarbon years means that no calibration curve has been used − the calculations for radiocarbon years assume that the , which for more than a decade after Libby's initial work was thought to be 5,568 years.
This was revised in the early 1960s to 5,730 years, which meant that many calculated dates in papers published prior to this were incorrect (the error in the half-life is about 3%).
radiation are similar to measurements for the rest of the biosphere.